- Increases ionic conductivity tenfold, enabling operation at room temperature and ensuring high-speed charging performance and fire safety - Achieved through joint research with research team of the late Professor John B. Goodenough, a Nobel laureate in Chemistry
SK On has succeeded in co-developing a polymer
electrolyte for lithium metal batteries that can operate at room temperature.
This achievement was made through the company’s collaboration with a research
team led by the late Professor John B. Goodenough from the University of Texas.
It is expected to contribute significantly to improving solid-state battery
performance and accelerate the development of all-solid-state batteries.
On June 16 (KST), SK On announced that it has
successfully developed a novel polymer electrolyte, the “SIPE (single-ion
conducting polymer electrolyte),” together with Professor Hadi Khani, a
Research Assistant Professor who worked in John B. Goodenough group.
Professor Goodenough is a pioneer in battery
technology who doubled the capacity of lithium-ion batteries. In 2019, he was
awarded the Nobel Prize in Chemistry at the age of 97, setting the record as
the oldest Nobel laureate. Since 2020, he had been working with SK On on the
joint development of “solid electrolytes” for lithium metal batteries until his
passing in June last year, after which Professor Khani took over the research
team.
The research has been published in the prestigious
Journal of Electrochemical Society.
Polymer electrolytes are considered as the
next-generation solid battery materials with low cost and easy manufacturing.
However, they have lower ionic conductivity compared to oxide and sulfide-based
electrolytes, which means they typically operate only at high temperatures of
70-80°C. Overcoming this limitation is one of the key challenges in the field.
SIPE solved this issue by improving ionic
conductivity* and lithium-ion transference number**. Compared to existing
polymer electrolytes, SIPE has increased room temperature ionic conductivity by
approximately ten times (1.1×10-4S/cm) and the lithium-ion transference number
from 0.2 to 0.92, nearly a fivefold increase. These improvements enable
operation at room temperature.
(*)Ionic conductivity: a measure of a material’s
tendency to conduct ions; higher values indicate easier ion movement within the
electrolyte
(**)Transference number: the proportion of current
carried by a particular ion; a higher lithium-ion transference number means
more lithium cations are moving
Higher ionic conductivity and lithium-ion transference
number enhance battery output and charging performance.
Experimental results showed that batteries applied
with SIPE maintain 77% of their discharge capacity during high-rate charging
and discharging (2C***) compared to low-rate charging and discharging (0.1C).
Solid electrolytes generally suffer from significant capacity loss during
high-rate charging due to low ionic conductivity, but SIPE minimizes this
issue.
(***)C-rate (charging and discharging rate): a unit
that indicates the speed of charging and discharging; a 1C rate during charging
means the battery charges to 100% capacity in one hour
It is noteworthy that the stability of the solid electrolyte
interphase (SEI) has been improved to suppress dendrite**** formation. Lithium
metal batteries can significantly increase energy density by using metal
lithium instead of graphite as the cathode. However, resolving the persistent
dendrite issue is essential for commercialization.
(****)Dendrite: tree-like crystalline structures that
accumulate on the cathode surface during the charging and discharging process
when lithium ions move between the anode and cathode; these structures are one
of the causes of reduced battery lifespan and safety
Additionally, SIPE has high mechanical durability,
making mass production possible. It also has excellent thermal stability,
withstanding temperatures above 250°C. When applied to next-generation hybrid
solid batteries, it is expected to improve charging speed and low-temperature
performance.
“Based on the results of this research, we expect to
accelerate the development of solid-state batteries applying polymer
electrolytes,” said Kim Tae-kyung, Head of the Next Generation Battery R&D
Center at SK On. He added, “SK On will seize growth opportunities in the
next-generation battery field by leveraging our competitive edge in new
material technologies.”
Meanwhile, SK On is developing two types of
all-solid-state batteries: polymer-oxide composites and sulfide-based
batteries. The goal is to produce pilot prototypes in 2025 and 2026,
respectively, and commercial prototypes in 2028 and 2029. The sulfide-based
next-generation battery pilot plant, currently under construction at the
company’s Battery Research Institute in Daejeon, South Korea, is expected to be
completed in the second half of next year.
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